This section focuses on an overview of cis-3-hexenyl hexanoate as well as its manufacturing processes and uses. Also, please check out the introduction to cis-3-hexenyl hexanoate manufacturers, supply chain issues, cis-3-hexenyl hexanoate suppliers, and cis-3-hexenyl hexanoate prices. Sinofi can help you buy high-quality cis-3-hexenyl hexanoate in bulk for your industry applications at wholesale prices based on FEMA 3403 and CAS 31501-11-8.
Table of Contents
What is Cis-3-Hexenyl Hexanoate?
Cis-3-hexenyl hexanoate is a naturally occurring ester compound that plays a significant role in the world of fragrances and flavours. It is an ester formed by the combination of cis-3-hexenol (also known as leaf alcohol) and hexanoic acid (caproic acid). Cis-3-hexenyl hexanoate features a double bond in the cis configuration at the third carbon position of the hexenyl chain, which is crucial for its characteristic olfactory properties. Known for its distinctive fresh, green, and fruity aroma, this chemical compound has become an essential ingredient in the perfume and food industries, capturing the essence of freshly cut grass and ripe fruits in a single molecule. According to the U.S. Food and Drug Administration (FDA), cis-3-hexenyl hexanoate is approved to be used in the food, flavour, and fragrance industries. It has also been evaluated by relevant regulatory authorities like JECFA, EUR-Lex, ECHACHEM, NIST, and WHO. The IFRA Transparency List provides guidelines for the use of cis-3-hexenyl hexanoate in the food, flavour, fragrance, and personal care industries.
Natural Occurrence
Cis-3-hexenyl hexanoate occurs naturally in various plants and fruits, contributing to their characteristic aromas. It can be found in:
- Apple varieties: Contributing to the fresh, fruity notes in apple fragrance.
- Banana: Adding to the complex bouquet of banana aroma.
- Tea plants: Present in green tea leaves, contributing to the fresh, grassy notes.
- Various herbs and leaves: Found in plants that exhibit green, leafy fragrances.
The compound is often produced by plants as part of their natural volatile organic compound (VOC) profile, which can serve various biological functions, including attracting pollinators, deterring herbivores, or facilitating plant-to-plant communication.
Sensory Profile
The olfactory profile of cis-3-hexenyl hexanoate is characterized by several distinct notes:
- Green and fresh: Reminiscent of newly cut grass or fresh leaves.
- Fruity: Sweet, apple-like characteristics with tropical undertones.
- Herbaceous: Crisp, vegetation-like qualities.
- Clean: A bright, airy quality that adds freshness to fragrance compositions.
This complex sensory profile makes it particularly valuable in creating natural-smelling fragrances that evoke outdoor environments and fresh produce.
CAS No.: 31501-11-8
According to the American Chemical Society, the CAS number of cis-3-hexenyl hexanoate is 31501-11-8.
CAS Name: cis-3-Hexenyl hexanoate
Molecular Formula: C12H22O2
Molecular Mass: 198.30
Appearance: Colourless to pale yellow, clear liquid
Boiling Point: 222.00 to 224.00 °C. @ 760.00 mm Hg
Solubility: Soluble in alcohol but slightly soluble in water.
Other Names:
♦ cis-3-Hexenyl caproate
♦ cis-3-Hexenyl hexoate
♦ 3-Hexenyl hexanoate, cis-
♦ Leaf hexanoate
Cis-3-Hexenyl Hexanoate Odour
Odour Strength: Medium
Substantivity:8 hours at 100.00 %
At 100.00 %. fruity green waxy pear winey tropical grassy pineapple
FEMA Number 3403
According to the Flavor and Extract Manufacturers Association (FEMA), the number of cis-3-hexenyl hexanoate is FEMA 3403.
Bulk Cis-3-Hexenyl Hexanoate Manufacturers
The bulk cis-3-hexenyl hexanoate manufacturing represents a dynamic sector within the broader fragrance and flavor chemicals market. Top cis-3-hexenyl hexanoate manufacturers like Givaudan maintain extensive R&D capabilities and have been investing heavily in both natural and synthetic ingredient production. Chinese manufacturers of cis-3-hexenyl hexanoate make China a significant production hub for this compound. It reflects the country’s role as a major chemical producer and its competitive manufacturing costs. This industry continues to evolve through technological innovation, sustainability initiatives, and expanding global demand.
Sinofi is a bulk manufacturer of cis-3-hexenyl hexanoate in China, and we have a manufacturing facility with 2,500 square meters for the production of cis-3-hexenyl caproate. We supply high-quality cis-3-hexenyl hexanoate at bulk prices and serve food, flavour, fragrance, and personal care industries worldwide.
Manufacturing Process of Cis-3-Hexenyl Hexanoate
Raw Materials and Feedstock
The manufacturing process requires two primary raw materials.
Cis-3-hexen-1-ol (Leaf Alcohol)
This can be obtained through several routes, including extraction from natural sources like tea leaves or synthetic production via the reduction of cis-3-hexenal. The synthetic route typically involves the aldol condensation of acetaldehyde followed by selective hydrogenation.
Hexanoic Acid (Caproic Acid)
Commercially available through the oxidation of hexanol or as a byproduct of fatty acid production. High-purity grades (≥98%) are preferred for fragrance applications.
Manufacturing Process
The most common industrial method for producing cis-3-hexenyl hexanoate is direct esterification, which involves the following steps:
Reactor Setup and Charging
- A jacketed glass-lined or stainless steel reactor equipped with efficient stirring, a reflux condenser, and temperature control is prepared.
- The reactor is charged with cis-3-hexen-1-ol and hexanoic acid in a slight excess (typically 1.1:1 molar ratio of acid to alcohol).
- An acid catalyst, usually sulfuric acid (0.5-1% by weight) or p-toluenesulfonic acid, is added.
Success in commercial production requires careful attention to reaction conditions, purification methods, and quality control to ensure a high-quality product that meets the demanding specifications of the fragrance and flavor industry.
Bulk Cis-3-Hexenyl Hexanoate Suppliers
The bulk supply of cis-3-hexenyl hexanoate reflects broader trends in the fragrance and flavour industries, with demand growing as consumer preferences shift toward natural, high-quality products. Top cis-3-hexenyl hexanoate suppliers, such as Givaudan, are the foremost fragrance and flavour companies worldwide. They provide a wide array of perfume ingredients and have extensive experience in sourcing, extracting, and synthesizing them. These companies maintain extensive portfolios of aroma chemicals and have established global distribution networks capable of handling large-volume orders.
Sinofi is a bulk cis-3-hexenyl hexanoate supplier in China, and we have a warehouse with 1,200 square meters for high-quality cis-3-hexenyl caproate. We sell different grades of cis-3-hexenyl hexanoate at wholesale prices to food, flavor, and fragrance manufacturers.
Supply Chain of Cis-3-Hexenyl Hexanoate
The supply chain for cis-3-hexenyl hexanoate exemplifies the complexity and sophistication of modern speciality chemical distribution networks. While the compound represents a small-volume product in the broader chemical industry, its supply chain reflects many of the key trends shaping the sector: consolidation among major players, growing importance of value-added services, increasing focus on sustainability, and the critical role of emerging markets.
Supply Chain Structure Overview
The cis-3-hexenyl hexanoate supply chain follows a multi-tiered structure typical of specialty chemicals.
Raw Material Suppliers
- Petrochemical feedstock providers.
- Agricultural derivative suppliers (for natural variants).
- Solvent and catalyst suppliers.
Cis-3-Hexenyl Hexanoate Manufacturers
- Large integrated chemical companies.
- Speciality aroma chemical producers.
- Contract manufacturers.
Cis-3-Hexenyl Hexanoate Distributors
- Global speciality chemical distributors.
- Regional flavour and fragrance distributors.
- Technical service providers.
End-User Industries
- Fragrance houses and flavour companies.
- Consumer goods manufacturers.
- Agricultural chemical companies.
As the flavours and fragrances industry continues to evolve, the supply chain for speciality chemicals such as cis-3-hexenyl hexanoate will need to adapt to changing consumer preferences, regulatory requirements, and environmental expectations while maintaining the reliability and technical support customers demand.
Wholesale and Buy Cis-3-Hexenyl Hexanoate in Bulk
cis-3-Hexenyl hexanoate represents a valuable compound for businesses in the fragrance, flavour, and emerging agricultural sectors. Successful bulk purchasing of cis-3-hexenyl hexanoate requires understanding its applications, identifying reliable suppliers, and implementing appropriate quality and logistical controls. Buyers of cis-3-hexenyl hexanoate should build strong relationships with certified suppliers and implement robust quality control measures. They should also stay informed about market developments to optimize their procurement strategies. Whether sourcing from established multinational corporations or emerging regional suppliers, buyers must balance cost considerations with quality requirements and supply security to ensure optimal outcomes for their specific applications.
Bulk Purchasing Considerations
Quality Specifications
When purchasing cis-3-hexenyl hexanoate in bulk, buyers should specify:
- Purity levels (typically 95-99% for commercial applications).
- Isomer composition (the cis isomer should constitute at least 98% of the total composition).
- Certificate of Analysis requirements.
- Shelf life and storage conditions.
Supplier Evaluation
When selecting bulk suppliers, consider:
- Quality consistency, and batch-to-batch variation.
- Regulatory compliance and documentation.
- Supply chain reliability and delivery schedules.
- Technical support and formulation assistance.
As a bulk manufacturer and supplier of cis-3-hexenyl hexanoate in China, we supply high-quality cis-3-hexenyl caproate for food, flavour, and fragrance industries. We also wholesale cis-3-hexenyl hexanoate to small customers. Normally, they want to buy cis-3-hexenyl hexanoate in small quantities. To serve them, we can wholesale cis-3-hexenyl hexanoate at bulk prices and provide a one-stop purchasing service.
Cis-3-Hexenyl Hexanoate Prices (USD/Kg)
Food Grade Cis-3-Hexenyl Hexanoate Prices (FCC, GC Content >=99.0%)
| Volume | Unit Price | Shipment |
| 50g | 22 USD | Express |
| 500g | 112 USD | Express |
| 1Kg | 160 USD/Kg | Express |
| 20Kg | 20% cheaper | Express |
| 100Kg-Above | negotiable | Express / Sea |
Food Grade Cis-3-Hexenyl Hexanoate Natural Prices (FCC, GC Content >=95.0%)
| Volume | Unit Price | Shipment |
| 50g | 92 USD | Express |
| 500g | 462 USD | Express |
| 1Kg | 660 USD/Kg | Express |
| 20Kg | 20% cheaper | Express |
| 100Kg-Above | negotiable | Express / Sea |
Cis-3-hexenyl hexanoate prices are influenced by strong demand from the expanding fragrance and flavor industries, with the global perfume ingredient chemicals market projected to grow at 5-6% annually through 2030. The pricing environment for cis-3-hexenyl hexanoate reflects the dynamic nature of the speciality chemicals market, with prices influenced by raw material costs, regional demand patterns, and the ongoing shift toward natural ingredients. While specific pricing for cis-3-hexenyl hexanoate remains proprietary to suppliers, industry trends suggest continued growth in demand, which should support stable to rising prices for this valuable fragrance and flavour compound.
Furthermore, the above price quotations of cis-3-hexenyl hexanoate, especially for small orders, do not include the express shipping fee. The reason is that the shipment cost of cis-3-hexenyl hexanoate may exceed the value of the sample. However, the bulk wholesale prices of cis-3-hexenyl hexanoate will be much lower than those of small orders. Please contact us for more details.
Cis-3-Hexenyl Hexanoate Uses
Fragrance Uses
In perfumery and cosmetic fragrances, cis-3-hexenyl hexanoate is a key ingredient in creating green, fresh accords. Perfumers utilize this ester to add natural-smelling top notes that provide an immediate impression of freshness and vitality. It blends exceptionally well with other green notes, citrus oils, and floral components, making it a versatile building block for various fragrance types. The compound is particularly valuable for creating fragrances that aim to capture the essence of fresh-cut grass, green leaves, or crisp apples. Its ability to provide depth and complexity to green compositions while maintaining a natural character makes it indispensable in modern perfumery.
Flavor Uses
In the food and beverage industry, cis-3-hexenyl hexanoate serves as a flavouring agent that contributes to fruit-forward profiles, particularly apple, pear, and other green fruit flavours. Food technologists incorporate this ester into products in which a fresh, natural fruit character is desired, without the cloying sweetness often associated with synthetic fruit flavours. The compound finds applications in various food products, including beverages, confectionery, baked goods, and dairy products. Its ability to enhance perceived freshness makes it particularly useful for products marketed as natural or fresh-tasting.
Personal Care Uses
Beyond direct flavour and fragrance applications, cis-3-hexenyl hexanoate serves important functions in household products, including air fresheners, cleaning products, and personal care items, where its fresh, clean scent profile enhances product appeal and consumer acceptance. It is also used in the agricultural chemical industry.
Safety and Regulatory Considerations
Cis-3-hexenyl hexanoate is generally recognized as safe for use in food, flavour, fragrance, and personal care applications when used within established guidelines. Regulatory bodies such as the FDA and European authorities have evaluated this compound and approved its use in specified concentrations for flavor and fragrance applications. Proper handling procedures should be followed during manufacturing and formulation processes, including appropriate ventilation and personal protective equipment. It should be stored in cool, dry conditions away from sources of ignition and incompatible materials.
The demand for cis-3-hexenyl hexanoate continues to grow alongside increasing consumer preferences for natural-smelling and natural-tasting products. As manufacturers seek to create more authentic sensory experiences while meeting clean-label demands, this versatile ester remains an important tool for formulators.
Cis-3-Hexenyl Hexanoate Benefits
Benefits for Fragrance and Personal Care Products
Enhanced Sensory Experience
One of the primary benefits of cis-3-hexenyl hexanoate lies in its ability to create complex, appealing fragrance profiles. Its green, fresh character adds natural authenticity to synthetic compositions, bridging the gap between artificial and natural scents.
Longevity and Stability
Unlike some volatile aromatic compounds, cis-3-hexenyl hexanoate demonstrates good stability in various formulations, providing lasting fragrance in perfumes, cosmetics, and personal care products. This stability translates to longer-lasting products and better consumer satisfaction.
Skin Compatibility
The compound generally exhibits good skin tolerance, making it suitable for use in lotions, creams, and other topical applications. Its mild nature reduces the likelihood of skin irritation compared to some synthetic alternatives.
Environmental Benefits
Biodegradability
As a naturally occurring compound, cis-3-hexenyl hexanoate typically exhibits good biodegradability, making it a more environmentally friendly option than some synthetic alternatives.
Renewable Source Potential
The compound can be derived from natural plant sources or produced through green chemistry methods, supporting sustainable manufacturing practices.
Industrial Benefits
Versatile Formulation
The compound’s compatibility with various solvents and other ingredients makes it easy to incorporate into a range of formulations, from alcohol-based perfumes to oil-based personal care products.
Cost-Effectiveness
Compared to some rare natural extracts, cis-3-hexenyl hexanoate offers an economical way to achieve desired aromatic profiles without compromising quality.
Cis-3-Hexenyl Hexanoate Used in Flavour and Fragrance
A Tobacco Flavour with Oolong Tea Flavour
Include the following ingredients (Total 100 parts, by weight)
Dimethyl sulfide, 0.15 parts;
Isobutyraldehyde, 0.15 parts;
Acetic acid, 0.225 parts;
Isovaleraldehyde, 0.12 parts;
Isoamyl alcohol, 0.15 parts;
Butyric acid, 0.075 parts;
2-Methylpyrazine, 0.225 parts;
2,5-Dimethylpyrazine, 1.5 parts;
2,3,5-Trimethylpyrazine, 0.3 parts;
Phenylacetaldehyde, 0.12 parts;
2-Acetylpyrrole, 0.15 parts;
Octanol, 0.09 parts;
2-Ethyl-3,5-dimethylpyrazine, 0.075 parts;
Linalool, 0.45 parts;
Maltol, 1.5 parts;
Phenylethanol, 0.0 98 parts;
Indole, 0.0294 parts;
Benzyl acetate, 0.294 parts;
D, L-menthol, 0.049 parts;
Ethyl maltol, 0.98 parts;
Linalyl acetate, 0.098 parts;
4-Methyl-5-hydroxyethylthiazole, 0.049 parts;
Anisyl alcohol, 0.049 parts;
Cis-3-hexenyl hexanoate, 0.196 parts;
Alpha-Ionone, 0.0294 parts;
Dihydroactinidiolide, 0.294 parts;
Delta-Dodecalactone, 0.147 parts;
Methyl palmitate, 0.49 parts;
Oolong tea extract, 19.6 parts;
Organic solvent propylene glycol, 72.3172 parts.
In conclusion, cis-3-hexenyl hexanoate represents a valuable compound that successfully bridges natural authenticity with industrial practicality. As a bulk manufacturer and supplier of cis-3-hexenyl hexanoate in China, we offer various grades at wholesale prices to large manufacturers and small customers worldwide.