This section focuses on an overview of ligustral (triplal or ivy carbaldehyde) as well as its manufacturing processes and uses. Also, please check out the introduction to ligustral manufacturers, supply chain issues, ligustral suppliers, and ligustral prices. Sinofi can help you buy high-quality ligustral in bulk for industry applications at wholesale prices based on FEMA 4505 and CAS 68039-49-6 (ligustral), 27939-60-2(ivy carbaldehyde).
Table of Contents
What is Ligustral?
Ligustral, also known as 2,4-ivy carbaldehyde, represents a significant chemical compound in the fragrance and flavor industry. It is also marketed under various trade names, including Triplal, Cyclal C, Tricyclal, and Zestover. Ligustral has established itself as an essential ingredient in numerous consumer products worldwide. Ligustral and ivy carbaldehyde are classified as aromatic aldehydes, and they exhibit a molecular structure that contributes to their unique olfactory properties, featuring an aldehyde functional group attached to an aromatic ring system. The compound exists as a mixture of two isomers, with the main component being 2,4-dimethyl-3-cyclohexene formaldehyde, accounting for approximately 80% of the mixture and delivering a strong green aroma like cis-3-Hexenol. This powerful green odor profile includes fresh cucumber and citrus notes, making it particularly valuable for creating natural, fresh scents in various applications. These characteristics enable ligustral to blend effectively with various formulation components while maintaining stability under normal storage and processing conditions. Ligustral demonstrates moderate volatility, making it suitable for both top and middle note applications in fragrance compositions. Its chemical stability allows for extended shelf life in finished products while maintaining consistent scent delivery throughout the product’s lifecycle. According to the U.S. Food and Drug Administration (FDA), ligustral is approved to be used in the flavour, fragrance, personal care, and cosmetic industries.
Safety and Regulatory Considerations
Ligustral has functional use as flavor and fragrance agents, indicating its acceptance by regulatory authorities for these specific purposes. Regulatory bodies, including the JECFA and the International Fragrance Association (IFRA), have evaluated ligustral (2,4-dimethyl-3-cyclohexen-1-carboxaldehyde) and ivy carbaldehyde (Dimethylcyclohex-3-ene-1-carbaldehyde (isomer unspecified)). They established acceptable use levels. It has also been evaluated by relevant regulatory authorities like RIFM and ECHACHEM. The EU Cosmetics Regulation requires that 26 specific fragrance allergens must be declared on product labels if present at concentrations above 0.001% in leave-on products or 0.01% in rinse-off products. While ligustral is not currently listed among these 26 mandatory disclosure allergens.
Natural Sources and Occurrence
Ligustral occurs naturally in several plant species, most notably within the Ligustrum genus, commonly known as privet plants. These evergreen shrubs, belonging to the olive family Oleaceae, produce ligustral as part of their natural aromatic compounds. The compound contributes to the characteristic fragrance of privet flowers, which bloom in dense clusters during late spring and early summer. Beyond privet plants, ligustral has been identified in various other botanical sources, though typically in lower concentrations.
Aromatic Profile
The compound’s distinctive olfactory profile combines fresh, green notes with subtle citrus undertones. This unique scent profile makes it particularly valuable for creating complex fragrance compositions.
CAS No.: 68039-49-6 or 27939-60-2
According to the American Chemical Society, ligustral is available under CAS numbers 68039-49-6 or 27939-60-2.
CAS Name: 2,4-Dimethyl-3-Cyclohexene Carboxaldehyde
Molecular Formula: C9H14O
Molecular Mass: 138.21
Appearance: Colorless to light yellow, clear liquid
JECFA number: 1900
Boiling Point: 196.00 °C. @ 760.00 mm Hg
Solubility: Soluble in alcohol, dipropylene glycol. Slightly soluble in water (311.5 mg/L @ 25 °C)
Other Names:
♦ Tripral
♦ Cyclal C
♦ Tricyclal
♦ Triplal
♦ Ligustral
♦ Zestover
♦ (Z)-Vertocitral C
♦ Nvzhenquan
♦ 2,4-Dimethyl-3-cyclohexenecarboxaldehyde
♦ 2,4-Dimethyl-3-cyclohexenylcarbaldehyde
♦ 2,4-Dimethylcyclohex-3-ene-1-carbaldehyde
♦ 2,4-Dimethyl-cyclohex-3-enecarbaldehyde
♦ 2,4-Ivy carbaldehyde
Ligustral Odor
Odor Strength: High, recommend smelling in a 10.00 % solution or less
Substantivity: 8 hours at 100.00 %
At 10.00 % in dipropylene glycol, green aldehydic leafy fresh nasturtium, cortex, grassy
FEMA Number 4505
According to the Flavor and Extract Manufacturers Association (FEMA), the number of ligustral is FEMA 4505.
Bulk Ligustral Manufacturers
The bulk ligustral manufacturing landscape features a diverse mix of established fragrance companies and specialized chemical producers. Top ligustral manufacturers like Givaudan and IFF adhere to stringent quality standards to meet the demanding requirements of the fragrance and cosmetics industries. China has established itself as a major hub for ligustral production. These Chinese manufacturers typically provide ligustral in stock with competitive pricing and warranty provisions.
Sinofi is a bulk ligustral manufacturer in China, and we have a manufacturing facility with 2,500 square meters for the production of ligustral. We supply high-quality ligustral at bulk prices and serve the flavour, fragrance, personal care, and cosmetic industries worldwide.
Manufacturing Process of Ligustral
Ligustral is synthesized continuously in a fixed-bed reactor using 2-methyl-1,3-pentadiene and acrolein as raw materials and modified Al2O3 as a catalyst.
The raw materials of 2-methyl-1,3-pentadiene and acrolein are mixed, and then the mixed liquid is pumped to a fixed-bed reactor. They react under the action of the catalyst in the reactor, and then the reaction liquid is cooled, collected, and distilled to obtain pure ligustral.
Bulk Ligustral Suppliers
The bulk ligustral supply is served by a diverse network of suppliers ranging from large multinational flavour and fragrance companies to specialized chemical manufacturers. Top ligustral suppliers like Givaudan and IFF operate across different geographical regions and offer varying levels of quality, pricing, and service. Chinese suppliers have emerged as major players in the ligustral supply chain. They typically offer competitive pricing and large-scale production capabilities, serving both domestic and international markets.
Sinofi is a bulk ligustral supplier in China, and we have a warehouse with 1,200 square meters for high-quality ligustral. We sell different grades of ligustral at wholesale prices to flavour, fragrance, personal care, and cosmetic manufacturers.
Supply Chain of Ligustral
The ligustral supply chain represents a complex network that transforms raw chemical materials into finished fragrance products distributed across global markets. For ligustral specifically, the supply chain follows this fundamental framework while addressing the unique requirements of chemical manufacturing and fragrance industry applications.
The future of the ligustral supply chain will be shaped by technological advancement, sustainability requirements, and evolving market demands. Organizations that successfully adapt their supply chain structures to address these factors will be best positioned to capitalize on the continued growth in fragrance and personal care markets worldwide.
Wholesale and Buy Ligustral in Bulk
Wholesale and bulk purchasing of ligustral requires careful consideration of multiple factors, including supplier selection, quality assurance, pricing strategies, and regulatory compliance. Success in ligustral procurement depends on developing comprehensive supplier relationships, implementing robust quality control procedures, and maintaining current knowledge of market conditions and regulatory requirements.
Wholesale Purchasing Considerations
When engaging in wholesale procurement of ligustral, buyers should carefully evaluate several critical factors to ensure successful purchasing outcomes. Product quality specifications represent the foundation of any wholesale agreement, with buyers typically requiring purity levels of 99% or higher and specific physical characteristics, including appropriate color, odor intensity, and chemical stability. Pricing structures for wholesale ligustral purchases generally follow volume-based tiers, with significant cost reductions available for larger order quantities.
Bulk Buying Strategies
Successful bulk purchasing of ligustral requires strategic planning and careful supplier evaluation. Buyers should establish clear procurement objectives that balance cost efficiency with quality requirements and delivery reliability. Annual consumption forecasting helps determine optimal order quantities and timing to minimize inventory carrying costs while avoiding supply disruptions.
Supplier diversification represents a crucial risk management strategy for bulk buyers. Establishing relationships with multiple qualified suppliers provides supply security and competitive pricing leverage. Due diligence should include verification of manufacturing capabilities, quality certifications, financial stability, and compliance with relevant industry standards.
Contract negotiations for bulk purchases should address key terms, including pricing mechanisms, quality specifications, delivery schedules, payment terms, and force majeure provisions. Long-term supply agreements can provide price stability and guaranteed allocation, particularly beneficial for manufacturers with consistent ligustral requirements.
Quality Assurance and Testing
Quality assurance protocols are essential for wholesale ligustral procurement, given their direct impact on final product performance. Buyers should implement comprehensive testing procedures that verify chemical purity, organoleptic properties, and physical characteristics upon receipt of each shipment. Documentation requirements for quality assurance typically include supplier certificates of analysis, internal test reports, and batch-tracking records. These documents support regulatory compliance efforts and provide traceability for quality investigations if issues arise during product use.
As a bulk ligustral manufacturer and supplier in China, we supply high-quality 2,4-ivy carbaldehyde for flavour, fragrance, personal care, and cosmetic industries. We also wholesale ligustral to small customers. Normally, they want to buy ligustral in small quantities. To serve them, we can wholesale ligustral at bulk prices and provide a one-stop purchasing service.
Ligustral Prices (USD/Kg)
Food Grade Ligustral Prices (GC Content >=99.0%)
| Volume | Unit Price | Shipment |
| 50g | 7 USD | Express |
| 500g | 32 USD | Express |
| 1Kg | 45 USD/Kg | Express |
| 20Kg | 20% cheaper | Express |
| 100Kg-Above | negotiable | Express / Sea |
Current market data indicates that ligustral prices vary significantly based on purity levels and application requirements. Industrial-grade compounds typically command lower prices compared to those of high purities, which require higher purity specifications and more stringent quality control measures. The ligustral market benefits from several positive trends. Increasing consumer preferences for innovative scent combinations drive demand for specialty fragrance ingredients. The premium and niche fragrance segments demonstrate particular strength, as consumers seek personalized experiences and unique product offerings.
Furthermore, the above ligustral price quotations do not include the express shipping fee. The reason is that the shipment cost of ligustral may exceed the value of the sample. However, the bulk wholesale ligustral prices will be much lower than those of small orders. Please contact us for more details.
Ligustral Uses
Ligustral represents a significant aromatic aldehyde compound with diverse applications across multiple industries.
Flavour and Fragrance Uses
The fragrance industry represents one of the primary commercial applications for ligustral. It pairs well with floral, woody, and grassy scents and works very well with citrus oils.
In the flavour industry, ligustral functions as an intermediate in the production of compounds that contribute to food and beverage flavouring. The compound’s aromatic properties make it suitable for creating vanilla-like and other pleasant flavour notes when properly processed and incorporated into flavour formulations.
Pharmaceutical and Medicinal Uses
Ligustral serves as a valuable intermediate in pharmaceutical synthesis, particularly in the development of compounds with potential therapeutic properties. The presence of both hydroxyl and aldehyde functional groups provides multiple sites for chemical modification, allowing medicinal chemists to create derivatives with enhanced biological activity or improved pharmacological properties.
Research applications include the synthesis of compounds with anti-inflammatory, antimicrobial, and antioxidant properties. The compound’s structure makes it suitable for creating molecules that can interact with biological systems in therapeutically beneficial ways.
Chemical Synthesis Uses
The chemical industry employs ligustral as an intermediate in the production of various specialty chemicals. Its reactive functional groups make it useful in the synthesis of polymers, resins, and other materials with specific properties. The compound participates in condensation reactions, oxidation processes, and other chemical transformations that yield products with commercial value.
Agricultural Uses
Ligustral finds use in the development of agricultural chemicals, including certain pesticide formulations and plant growth regulators. The compound’s ability to undergo various chemical modifications allows for the creation of molecules with specific biological activities that benefit crop protection and agricultural productivity.
Ligustral Benefits
Fragrance Enhancement
Ligustral provides a distinctive floral scent profile characterized by fresh, green, and lily-of-the-valley notes. This makes it particularly valuable for creating sophisticated fragrance compositions that require a natural, springtime character. The compound serves as both a standalone fragrance note and a harmonizing element that enhances other floral components in complex formulations.
Stability and Longevity
One of Ligustral’s key advantages is its chemical stability, which translates to consistent performance in finished products. Unlike some natural fragrance materials that may degrade over time, Ligustral maintains its olfactory properties throughout typical product shelf life, ensuring reliable scent delivery for end consumers.
Cost-Effective Alternative
Ligustral provides an economical alternative to natural lily-of-the-valley extracts, which are expensive and difficult to obtain in commercial quantities. This synthetic option allows manufacturers to achieve desired fragrance profiles while maintaining competitive pricing structures.
Ligustral Used in Flavour and Fragrance
A Green Apple Flavour for Personal Care Products
Include the following ingredients (by weight):
Ethyl 2-methylbutyrate, 0.2 parts; trans-2-hexenal, 0.005 parts; hexanol, 0.001 parts; trans-2-hexenol, 0.02 parts; isoamyl acetate, 0.15 parts; ethyl acetoacetate, 0.15 parts; isopentyl acetate, 0.055 parts; benzaldehyde, 0.001 parts; cis-3-hexenyl acetate, 0.015 parts; isocyclocitral, 0.33 parts; dimethyl benzyl carbinol, 0.004 parts; benzyl acetate, 0.003 parts; isononyl acetate, 0.05 parts; allyl heptanoate, 3 parts; styralyl acetate, 0.5 parts; citronellol, 0.006 parts; cis-3-hexenol 2-cyano-3-methyl-2-butenoate, 4.6 parts; pine acetate, 0.02 parts; citronellyl acetate, 0.2 parts; neryl acetate, 0.001 parts; butyl damascone, 0.004 parts; geranyl acetate, 0.005 parts; allyl cyclohexyl propionate, 0.33 parts; methyl ionone, 0.5 parts; dimethyl benzyl butyrate, 0.26 parts; phenoxyethyl isobutyrate, 2.25 parts; lily aldehyde, 0.8 parts; peach aldehyde, 1.6 parts; methyl amyl cinnamaldehyde, 0.2 parts; hexyl salicylate, 0.5 parts; galaxolide, 0.3 parts; hibiscus lactone, 0.05 parts; privet aldehyde, 0.6 parts; kasiski, 0. .35 parts; dipropylene glycol, 82.92 parts.
In conclusion, ligustral has become increasingly important for perfume manufacturers, cosmetic companies, and aroma producers worldwide. As a bulk ligustral manufacturer and supplier in China, we sell different grades of ligustral at wholesale prices to large manufacturers and small customers worldwide.