This section provides an overview of linalyl acetate, covering its manufacturing processes, regulatory status, and applications in the food, flavour, perfumery, personal care, household, and aromatherapy industries. Also, please check out the introduction to linalyl acetate manufacturers, supply chain issues, linalyl acetate suppliers, and linalyl acetate prices. Sinofi can help you buy linalyl acetate at bulk wholesale prices based on FEMA 2636 and CAS 115-95-7.
Table of Contents
What is Linalyl Acetate?
Linalyl acetate is one of the most widely used esters in the flavour and fragrance industry. As the acetate ester of linalool, it delivers a soft, sweet, floral-fruity character with an unmistakable bergamot and lavender nuance. Its balanced volatility, pleasant odour, and broad regulatory acceptance make it a workhorse ingredient in both taste and aroma formulation. Linalyl acetate is formed by the esterification of the tertiary alcohol linalool with acetic acid. Because the hydroxyl group of linalool sits on a tertiary carbon bearing a vinyl group, the resulting ester is characteristically prone to acid-catalysed rearrangement and hydrolysis, a point of considerable practical importance during formulation. According to the U.S. Food and Drug Administration (FDA), linalyl acetate is approved to be used in the flavour and fragrance industries.
Regulatory Status and Safety Considerations
Linalyl acetate has been evaluated by major regulatory bodies like JECFA, EFSA, RIFM, ECHACHEM, NIST, IFRA, and WHO. It is well established within global regulatory frameworks:
- It is FEMA GRAS (FEMA 2636) for use as a flavouring substance.
- It is recognised by regulators including the U.S. FDA and is evaluated by JECFA within the relevant ester group.
- In fragrance applications, it is subject to IFRA guidance, and its dermal safety profile is supported by standard toxicological review.
As a formulation engineer, one should always confirm the current maximum use levels and any regional restrictions applicable to the specific product category, and rely on the supplier’s up-to-date specification, certificate of analysis, and safety data sheet. Users with skin sensitivity to fragrance materials should be considered where topical exposure is relevant.
Sensory Profile
From a flavourist’s perspective, linalyl acetate contributes:
- Odour: Fresh, sweet, floral, and fruity with a distinct bergamot-lavender tonality and a subtle green nuance. It is smoother and rounder than linalool itself, with less of the sharp, camphoraceous edge.
- Taste: At use levels, it lends citrus, floral, and slightly waxy-sweet notes, supporting bergamot, lemon, lavender, and tropical accords.
- Odour threshold: Low; the compound is perceptible at trace concentrations, so it exerts influence even at modest dosages.
Its role is frequently that of a rounding and lifting ingredient: it softens harsh top notes, adds natural floral depth, and bridges citrus and floral segments of a composition.
Natural Occurrence
Linalyl acetate is a major constituent of several commercially significant essential oils. It occurs abundantly in lavender and lavandin oils, bergamot oil, clary sage, petitgrain, and neroli, among others. In many of these oils it is the single largest component, which is why it contributes so strongly to their characteristic soft, sweet-floral signature.
For commercial use, the material is available both as a natural isolate (fractionated or distilled from essential oils) and as a nature-identical synthetic produced by esterifying linalool. The synthetic route offers consistent quality, high purity, and cost stability, whereas natural-source material commands a premium where a “natural” label claim is required.
CAS No.: 115-95-7
According to the American Chemical Society, the CAS number of linalyl acetate is 115-95-7.
CAS Name: Linalyl acetate
Molecular Formula: C12H20O2
Molecular Mass: 196.29
Appearance: Colorless, clear liquid.
JECFA Number: 359
Food Chemicals Codex Listed: Yes
Boiling Point: 220.00 °C. @ 760.00 mm Hg
Solubility: Soluble in alcohol, most fixed oils; insoluble in water.
Other Names:
♦ 1,6-Octadien-3-ol, 3,7-dimethyl-, 3-acetate
♦ 1,6-Octadien-3-ol, 3,7-dimethyl-, acetate
♦ Linalool acetate
♦ Acetic acid linalool ester
♦ Bergamiol
♦ Bergamol
♦ Linalyl acetate
♦ 3,7-Dimethyl-1,6-octadien-3-yl acetate
♦ Bergamot mint oil
♦ 3-Acetoxy-3,7-dimethyl-1,6-octadiene
♦ (±)-Linaloyl acetate
♦ dl-Linalool acetate
♦ (±)-Linalyl acetate
♦ 1,5-Dimethyl-1-vinyl-4-hexenyl acetate
♦ 3,7-Dimethyl-1,6-octadien-3-ol acetate
Linalyl Acetate Odor
Odor Strength: Medium.
Substantivity: 20 hours at 100.00 %.
Odor Description: At 100.00 %, sweet green citrus bergamot lavender woody.
FEMA Number 2636
According to the Flavour and Extract Manufacturers Association (FEMA), the FEMA number of linalyl acetate is 2636.
Bulk Linalyl Acetate Manufacturers
The bulk production for linalyl acetate is expected to grow more dynamically through the coming decade. Asia Pacific represents the largest regional share of demand and production, supported by substantial manufacturing capacity in China. Top linalyl acetate manufacturers like DSM-Firmenich, Givaudan, Ernesto Ventos, NHU, and BASF combine large-scale synthetic manufacturing, integrated raw material supply, and extensive regulatory and quality infrastructure. They are typically the preferred suppliers for multinational brands requiring guaranteed volume, batch-to-batch consistency, and comprehensive compliance documentation. Emerging biotechnology firms are developing bio-based production routes, while Chinese manufacturers continue to expand their international footprint through competitive pricing and rising quality standards.
Sinofi is a bulk linalyl acetate manufacturer in China, and we have a manufacturing facility with 2,500 square meters for the production of linalyl acetate. We supply high-quality linalyl acetate at bulk prices and serve food, flavour, perfumery, personal care, household, and aromatherapy industries worldwide.
Manufacturing Process of Linalyl Acetate
The manufacture of linalyl acetate is a study in reconciling a simple target reaction, the acetylation of an alcohol, with the demanding reactivity of a tertiary allylic monoterpene substrate. Two structural features dominate the manufacturing chemistry. First, the hydroxyl group of linalool is tertiary, which renders it resistant to direct acid-catalysed esterification and prone to elimination. Second, the carbon bearing the hydroxyl group is allylic, which permits allylic rearrangement of the carbon skeleton. Both features must be actively managed throughout the process, as discussed below.
Raw Material: Sourcing of Linalool
Because linalyl acetate is manufactured almost exclusively by acetylation of linalool, the economics and quality of the ester are closely tied to the linalool feedstock. Industrial linalool is supplied predominantly by chemical synthesis, with two established platforms.
The Terpene (Pinene) Route
α- and β-Pinene, obtained from turpentine, provide a renewable terpene feedstock. β-Pinene is thermally cracked (pyrolysed) to myrcene, which is then converted through hydrochlorination and subsequent base- or amine-mediated hydrolysis into a mixture of acyclic monoterpene alcohols, including linalool, geraniol, and nerol. Fractional distillation separates the desired linalool fraction.
The Petrochemical (Dehydrolinalool) Route
The dominant large-scale route builds the terpene skeleton from simple petrochemical precursors. Acetone and acetylene chemistry is used to construct the appropriate C₁₀ intermediate, dehydrolinalool (an acetylenic tertiary alcohol). Selective partial hydrogenation of the triple bond over a poisoned palladium catalyst (a Lindlar-type catalyst) furnishes linalool while preserving the two carbon–carbon double bonds. This route offers high volume, consistent purity, and independence from agricultural supply variability.
Synthetic linalool from either route is typically racemic, whereas naturally derived linalool is enantiomerically enriched. This distinction carries through to the finished ester and is relevant to premium fragrance applications.
Biocatalytic (Enzymatic) Manufacturing
Enzyme-catalysed synthesis has emerged as an attractive, milder alternative that largely circumvents the rearrangement and dehydration problems. Immobilised lipases, most notably Candida antarctica lipase B (commercially available as Novozym 435), catalyse the acylation of linalool under near-neutral, low-temperature conditions.
The principal limitations are enzyme cost, reaction rates that are typically slower than those of chemical acylation, and sensitivity to reaction-medium water content, which must be controlled to favour esterification over hydrolysis.
Bulk Linalyl Acetate Suppliers
The bulk supply for linalyl acetate is positioned for continued growth, sustained by resilient demand across fragrance, personal care, household, and pharmaceutical applications. Top linalyl acetate suppliers like DSM-Firmenich, Givaudan, Ernesto Ventos, NHU, and BASF account for a substantial share of total revenue, reflecting a market with meaningful concentration at the top.
Sinofi is a bulk linalyl acetate supplier in China, and we have a warehouse with 1,200 square meters for high-quality linalyl acetate. We sell different grades of linalyl acetate at wholesale prices, serving end-users in food, flavour, perfumery, personal care, household, and aromatherapy industries.
Supply Chain of Linalyl Acetate
The defining characteristic of the linalyl acetate supply chain is its dual origin: the molecule is available both as a naturally extracted material, chiefly from lavender, lavandin, and bergamot, and as a synthetic material produced by esterification of linalool. These two pathways draw on entirely different upstream resources, cost structures, and risk profiles, yet converge on a functionally comparable end product.
Supply Chain Structure
The linalyl acetate value chain can be organized into four tiers: upstream feedstocks, midstream intermediates and conversion, manufacturing, and downstream distribution and end markets.
Upstream: Feedstocks
The natural stream begins with agricultural botanicals. Lavender and lavandin are the principal sources, with bergamot (Citrus bergamia) providing another linalyl-acetate-rich oil, alongside clary sage, ho wood, and petitgrain. These crops are geographically concentrated and seasonal: Bulgaria and France dominate European lavender and lavandin cultivation, bergamot is closely associated with the Calabria region of Italy, and China contributes additional volumes. Harvest windows are narrow, typically spanning a few weeks in July for lavender in the Northern Hemisphere, which limits flexibility and concentrates supply risk.
The synthetic stream draws on petrochemical feedstocks, principally isobutene and methanol, which are converted into citral, the central intermediate in the modern aroma-chemicals value chain. A secondary bio-based route derives linalool from pine turpentine (α- and β-pinene), a by-product of the pulp and paper industry.
Midstream: Intermediates and Conversion
In the natural stream, botanicals undergo steam distillation or cold expression to yield essential oils in which linalyl acetate is already present as a natural constituent. In the synthetic stream, citral is hydrogenated to linalool, which becomes the immediate precursor to linalyl acetate. Linalool itself is a high-volume aroma chemical in its own right, widely used in laundry and home care, so its availability and pricing are shaped by demand well beyond linalyl acetate alone. The final ingredient in the synthetic route is the acetylating agent, typically acetic acid or acetic anhydride.
Manufacturing
The two streams reach the finished molecule by different means. Natural linalyl acetate is concentrated through fractional distillation of the relevant essential oils. Synthetic linalyl acetate is produced through esterification (acetylation) of linalool, a mature and efficient chemical process that delivers consistent purity and odour profile at scale. Individual synthetic production lines are relatively modest in scale, commonly in the range of several hundred to around one thousand tonnes per year, with gross margins typically estimated at 15–25 percent.
Downstream: Distribution and End Markets
Finished linalyl acetate flows to the major flavour and fragrance houses and specialized aroma-chemical distributors, who incorporate it into fragrance compounds and flavour bases. These are supplied to brand formulators in the personal care, home care, cosmetics, and food and beverage sectors. Fragrances represent the single largest application by revenue, reflecting the molecule’s central role in lavender and citrus accords.
Wholesale and Buy Linalyl Acetate in Bulk
Buying linalyl acetate in bulk is, at its core, an exercise in disciplined category management. Linalyl acetate buyers should define the specification precisely, qualify suppliers rigorously, and secure volume-based pricing under well-structured contracts. In a category where quality and continuity directly affect the finished product’s consumer appeal, that discipline is not administrative overhead; it is a genuine source of competitive advantage.
Understanding the Product
Before issuing a purchase order, the buyer should confirm the intended application with internal stakeholders, because the required grade, purity, olfactive standard, and regulatory documentation differ meaningfully between a fragrance house, a household cleaning product manufacturer, and a flavour application governed by food-grade requirements.
The market is conventionally segmented along three axes:
- By type: natural versus synthetic. Natural grades command a premium and are directed toward prestige fragrance and clean-label positioning, while synthetic grades dominate high-volume, cost-sensitive applications.
- By application: fragrances (the largest revenue share), cosmetics and personal care, soaps and detergents, home care, and flavours.
- By purity: technical grades for functional products versus high-purity grades for fine fragrance and flavour use.
Why Bulk Purchasing Makes Commercial Sense
The economics of aroma chemical procurement favor volume. Suppliers commonly tier their pricing across pack sizes ranging from 25-kilogram drums to 180-kilogram drums, 1,000-kilogram IBC totes, and full ISO tank quantities, with per-kilogram costs falling considerably at each threshold. Beyond the headline price, bulk purchasing reduces per-unit freight, handling, and customs clearance costs, consolidates quality control effort into fewer incoming lots, and strengthens the buyer’s position in annual contract negotiations.
Bulk buying also serves as a hedge against supply volatility. Linalyl acetate pricing is influenced by upstream feedstock costs, essential oil harvest outcomes in the case of natural material, energy prices, and freight conditions.
Qualifying Wholesale Suppliers
Supplier qualification is the foundation of a reliable program. A credible wholesale supplier should provide, as a matter of routine, a Certificate of Analysis for each lot, a current Safety Data Sheet, and specifications covering purity by gas chromatography, appearance, refractive index, specific gravity, optical rotation where relevant, and an olfactive evaluation against an agreed standard. For fragrance applications, confirmation of compliance with current IFRA standards is essential; for flavour use, FEMA GRAS status and food-grade manufacturing conditions must be documented.
As a bulk linalyl acetate manufacturer and supplier in China, we wholesale this ingredient to end users in food, flavour, perfumery, personal care, household, and aromatherapy industries. We also supply linalyl acetate to small customers. Normally, they want to buy linalyl acetate in small quantities. To serve them, we can sell linalyl acetate at bulk prices and provide a one-stop purchasing service.
Linalyl Acetate Prices (USD/Kg)
Food Grade Linalyl Acetate Prices (GC Content >=97.0%)
| Volume | Unit Price | Shipment |
| 50g | 6 USD | Express |
| 500g | 32 USD | Express |
| 1Kg | 47 USD/Kg | Express |
| 25Kg | 33 USD/Kg | Express |
| 100Kg | 29 USD/Kg | Express / Sea |
| 200Kg-Above | negotiable | Express / Sea |
Linalyl acetate trades in two distinct tiers: synthetic linalyl acetate prices recorded roughly USD 20–50/kg in EU and American countries, versus natural grade at USD 250–400/kg. For orders of synthetic linalyl acetate exceeding 10 metric tons, major manufacturers can offer discounts of up to 50% off the ex-works price. Prices were elevated during the 2021–2023 inflation and European energy crisis, then eased as feedstock costs normalized and the fragrance and flavour industry worked through a severe 2023–2024 destocking cycle.
Furthermore, the above price quotations of linalyl acetate do not include the express fee. The reason is that the shipment cost may exceed the sample value of linalyl acetate. However, the bulk wholesale prices of linalyl acetate will be much lower than those of small orders. Please contact us for more details.
Linalyl Acetate Specification
| Appearance | Colorless, clear liquid. |
| Odor: | Sweet green citrus bergamot lavender woody. |
| Purity (GC) | >=97% |
| Acid Value (mg KOH/g) | <=0.3 |
| Refractive Index (20°C) | 1.448 – 1.452 |
| Specific Gravity (at 25℃/25℃) | 0.895 – 0.914 |
| Solubility | 1ml sample is dissolved in 5ml 70% ethanol |
Linalyl Acetate Uses
Linalyl acetate occupies a significant place across a diverse array of industries by virtue of its appealing aroma, natural abundance, and reliable availability through synthesis. From fine perfumery and everyday cosmetics to aromatherapy, food flavouring, and household goods, it serves consistently as a valued fragrance and flavour material.
Applications in Fragrance
Linalyl acetate is a cornerstone of several classical fragrance structures:
- Lavender and fougère accords, where it provides the sweet, fresh heart that defines the family.
- Colognes and citrus compositions, contributing roundness and bridging top and heart notes.
- Chypre and floral bases, where it softens and adds lift.
- Functional perfumery for soaps, detergents, fabric care, and air care, valued for its pleasant character and reasonable cost.
Its moderate volatility positions it as a heart note that also supports the top, improving the smoothness of the transition between the initial impact and the body of a fragrance.
Applications in Flavour
In flavour work, linalyl acetate is a versatile modifier used at low levels. Typical roles include:
- Citrus profiles — reinforcing bergamot, lemon, and orange notes and adding natural sweetness.
- Berry and stone-fruit systems — contributing floral-fruity nuance to blueberry, peach, and apricot.
- Tea flavours, particularly Earl Grey, where the bergamot association is essential.
- Herbal and lavender-flavoured products, confectionery, and baked goods.
Because the material is potent, dosing is normally in the low parts-per-million range in the finished product, and it is best evaluated in dilution to avoid overwhelming a composition.
Cosmetics and Personal Care
Beyond concentrated perfumery, linalyl acetate features prominently in a broad range of cosmetic and personal care products. It is incorporated into soaps, shampoos, conditioners, lotions, deodorants, shower gels, and other toiletries, primarily to impart a pleasant scent and to mask the less desirable base odours of raw formulation ingredients. Its stability within typical product matrices and its compatibility with other common fragrance materials make it a practical choice for large-scale manufacturing.
Aromatherapy and Wellness
Linalyl acetate has attracted attention within aromatherapy and wellness contexts, largely owing to its prominence in lavender and bergamot oils, both of which are traditionally associated with relaxation and stress relief. Some studies have investigated the compound and the oils rich in it for potential calming, sedative, and mood-supporting effects, and preliminary research has explored anti-inflammatory and other biological activities.
Household and Industrial Products
The clean, pleasant scent of linalyl acetate also lends itself to household and industrial goods. It is frequently found in air fresheners, scented candles, detergents, fabric softeners, surface cleaners, and other domestic products, where it provides fragrance and helps to convey an impression of cleanliness and freshness. In these contexts, its role parallels its function in personal care items: it enhances the sensory experience of the product and improves consumer acceptance.
Linalyl Acetate Benefits
Linalyl acetate stands out as a versatile and highly regarded aroma compound whose appeal extends well beyond its pleasant scent. Current research points to promising calming, anti-inflammatory, antimicrobial, and antioxidant properties, and its long-standing role in fragrance and skincare underscores its practical value.
Calming and Stress-Relieving Properties
The most frequently cited benefit of linalyl acetate relates to its potential to promote relaxation. In aromatherapy, essential oils rich in linalyl acetate are commonly employed to ease tension, encourage a sense of calm, and support restful sleep. Laboratory and preliminary clinical studies have associated the compound with anxiolytic (anxiety-reducing) and sedative-like effects, and researchers have proposed that it may influence the nervous system in ways that reduce physiological markers of stress.
Anti-Inflammatory and Analgesic Potential
Several investigations have explored the anti-inflammatory and pain-relieving properties of linalyl acetate. Experimental studies suggest that the compound may help moderate inflammatory responses and reduce sensitivity to certain types of discomfort. This dual profile has attracted interest for potential applications in topical preparations intended to soothe minor aches and irritation.
Antimicrobial and Antioxidant Activity
Linalyl acetate has demonstrated antimicrobial activity against a variety of bacteria and fungi in laboratory research. This property contributes to the traditional use of linalyl-acetate-rich essential oils as natural preservatives and cleansing agents. In addition, the compound exhibits antioxidant characteristics, meaning it may help counteract oxidative stress caused by reactive molecules.
Linalyl Acetate in E-Liquid and Vaping Products
Linalyl acetate is an aromatic ester valued for its soft, floral character and its associations with lavender and bergamot. It is one of the most widely used aroma chemicals in perfumery, cosmetics, and food flavouring, and it also appears in a number of e-liquid formulations, where it contributes delicate floral and citrus nuances.
Role in E-Liquid Formulation
In e-liquids, linalyl acetate is employed as a flavouring agent rather than as a base ingredient. The base of most e-liquids consists of propylene glycol and vegetable glycerin, to which nicotine and flavourings may be added. Within this system, linalyl acetate typically appears at low concentrations and serves the following purposes:
- Floral and lavender character. It provides the soft, powdery floral notes associated with lavender-forward blends.
- Bergamot and citrus lift. Because it is a defining component of bergamot oil, it is frequently used to construct bergamot accords, including Earl Grey–style tea profiles.
- Rounding and complexity. In combination with other aroma chemicals, it can soften sharp edges and add depth to fruit, dessert, and beverage-inspired flavours.
As with most aroma chemicals, the perceived effect depends heavily on concentration. Small quantities contribute nuance, whereas higher levels can render a formulation soapy or overpowering.
Regulatory Status
The regulation of e-liquid flavourings varies considerably by jurisdiction and continues to evolve. In the United States, vaping products fall under the authority of the Food and Drug Administration, which requires premarket authorization for the sale of new tobacco products, including flavoured e-liquids. In the European Union, the Tobacco Products Directive establishes notification requirements, ingredient reporting, and certain composition limits. A number of jurisdictions have moved to restrict or prohibit characterizing flavours altogether.
Because these frameworks change frequently and differ from one region to another, manufacturers and consumers should consult current, jurisdiction-specific guidance rather than rely on general summaries. Ingredient acceptability in one market does not guarantee acceptability in another.
A Jasmine Tea Flavouring Formulation Using Linalyl Acetate
Include the following ingredients (by weight, total 100g):
Cis-3-hexenol: 1; Linalool: 0.5; Phenethyl Alcohol: 0.8; Alpha-Amylcinnamaldehyde: 2; Hexanal: 0.5; Benzyl Acetate: 0.5; Jasmine Absolute: 3; Neroli Oil: 0.5; Cis-3-Hexenyl Acetate: 0.5; Indole: 3; Geraniol: 1; Geranyl Acetate: 0.5; Linalyl Acetate: 0.3; Methyl Dihydrojasmonate: 3; Farnesol: 0.5; Alpha-Terpineol: 0.6; Beta-Damascone: 0.2; Beta-Ionone: 0.2; Benzyl Alcohol: 0.08; Cis-3-Hexenyl Benzoate: 0.05; Ethyl Maltol: 0.3; Methyl Anthranilate: 0.5; Methyl Benzoate: 0.05; Methyl Salicylate: 0.1; Ethanol: 80.32.
In conclusion, linalyl acetate plays an important role in the food, flavour, perfumery, personal care, household, and aromatherapy industries. As a bulk linalyl acetate manufacturer and supplier in China, we sell different grades of linalyl acetate at wholesale prices to clients around the world.