This section provides an overview of allyl amyl glycolate, covering its manufacturing processes and regulatory status, applications in fine fragrances, personal care, air fresheners, detergents, and household cleaning industries. Also, please check out the introduction to allyl amyl glycolate manufacturers, supply chain issues, allyl amyl glycolate suppliers, and allyl amyl glycolate prices. Sinofi can help you buy allyl amyl glycolate at bulk wholesale prices based on FEMA 2636 and CAS 67634-00-8.
Table of Contents
What is Allyl Amyl Glycolate?
Allyl amyl glycolate has become the industry’s reference material for the “green pineapple” effect: a piercing, juicy, unmistakably modern note that cuts through a composition from the first moment of evaluation. For formulation engineers, it represents a classic example of a trace-level power material — an ingredient that is rarely dosed above a fraction of one percent, yet frequently defines the entire character of a top note. Allyl amyl glycolate is the allyl ester of (amyloxy)acetic acid. The substance is therefore more precisely described as allyl (3-methylbutoxy)acetate, also written as prop-2-en-1-yl (3-methylbutoxy)acetate. Structurally, the molecule combines three features of formulation significance: a terminal allyl ester group, which contributes diffusivity and the characteristic “sharp” allylic odour effect; an ether oxygen in the alpha position, typical of the glycolate family; and a branched five-carbon chain that lends the fruity, slightly waxy body. According to the precisionFDA, allyl amyl glycolate is approved to be used in the fragrance industry.
Regulatory Status and Safety Considerations
Allyl amyl glycolate has been evaluated by major regulatory bodies like SCCP, RIFM, ECHACHEM, NIST, IFRA, EUR-Lex and CosIng. Although the pineapple-green profile might suggest flavour utility, allyl amyl glycolate is not a standard tool of the flavourist in the way that allyl caproate or ethyl butyrate are, and published listings frequently show no assigned FEMA number for it. Any contemplated use in a flavour context must therefore be preceded by a rigorous confirmation of current regulatory status in the target market, including FEMA GRAS, EU flavouring regulation, and any applicable national positive lists. In practice, the pineapple effect in flavours is normally built from other, well-established esters, and allyl amyl glycolate is best regarded as a perfumery material. With respect to fragrance-industry self-regulation, the material is not itself the subject of a use-level restriction under the IFRA Standards up to and including the recent amendments; however, as an allyl ester it falls under the long-standing requirement — reflected both in IFRA practice and in Annex III of the EU Cosmetics Regulation — that the free allyl alcohol content of the material must not exceed 0.1 percent.
Sensory Profile
The value of allyl amyl glycolate lies in the combination of its odor character and its technical performance. It is remarkably powerful even at low concentrations, and it radiates strongly in the top note of a composition while retaining sufficient tenacity to influence the heart of a fragrance. Allyl amyl glycolate is best understood as a layered effect. The dominant impression is an intense, juicy pineapple note, sharper and greener than the ripe pineapple character of allyl caproate. Beneath this sits a pronounced galbanum-like greenness. Its pineapple-galbanum profile is not naturalistic in the manner of a literal fruit reconstitution; rather, it imparts a stylized, energetic freshness that reads as modern, sparkling, and slightly abstract. This quality made it a signature of the fresh, sporty, and aquatic fragrance styles that rose to prominence in the 1990s and that remain commercially significant today.
CAS No.: 67634-00-8
According to the American Chemical Society, the CAS number of allyl amyl glycolate is 67634-00-8.
CAS Name: Allyl (3-methylbutoxy)acetate
Molecular Formula: C10H18O3
Molecular Mass: 186.25
Appearance: Colorless, clear liquid.
Boiling Point: 201.00 to 203.00 °C. @ 760.00 mm Hg
Solubility: Soluble in alcohol; insoluble in water.
Other Names:
♦ Acetic acid, 2-(3-methylbutoxy)-, 2-propen-1-yl ester
♦ Acetic acid, (3-methylbutoxy)-, 2-propenyl ester
♦ Allyl 2-(isopentyloxy)acetate
Allyl Amyl Glycolate Odor
Odor Strength: Medium, recommend smelling in a 10.00 % solution or less.
Substantivity: 84 hours at 100.00 %.
Odor Description: At 10.00 % in dipropylene glycol, a strong fruity aroma with a slight pineapple-like note.
Bulk Allyl Amyl Glycolate Manufacturers
The bulk production of allyl amyl glycolate is measured, with a durable growth rate. Top allyl amyl glycolate manufacturers like IFF, Ernesto Ventos, Firmenich, Symrise, Givaudan, and Lluch Essence combine large-scale synthetic manufacturing and integrated raw material supply. Asian manufacturers, principally in China, have expanded capacity to serve both domestic compounding industries and export markets. They supply the material at competitive price points.
Sinofi is a bulk allyl amyl glycolate manufacturer in China, and we have a manufacturing facility with 2,500 square meters for the production of allyl amyl glycolate. We supply high-quality allyl amyl glycolate at bulk prices and serve fine fragrances, personal care, air fresheners, detergents, and household cleaning industries worldwide.
Manufacturing Process of Allyl Amyl Glycolate
The manufacture of allyl amyl glycolate is an instructive example of classical ether and ester chemistry executed under the exacting demands of the fragrance industry. Although the underlying transformations, a Williamson etherification and a Fischer esterification, are venerable reactions, commercial success depends on disciplined control of temperature, water removal, catalyst behavior, and distillation conditions, together with strict management of residual allyl alcohol.
Raw Materials
The commercial synthesis relies on a small set of readily available feedstocks. Isoamyl alcohol (3-methyl-1-butanol) supplies the amyl ether moiety and is available in high purity from fusel oil recovery or from petrochemical hydroformylation routes. Chloroacetic acid, or its sodium salt, serves as the glycolate backbone precursor. Allyl alcohol (2-propen-1-ol), produced industrially by the hydrolysis of allyl chloride or the isomerization of propylene oxide, furnishes the ester alcohol.
Principal Synthetic Route: Etherification Followed by Esterification
The most widely practiced industrial route proceeds in two chemical stages: a Williamson ether synthesis to produce isoamyloxyacetic acid, followed by a Fischer esterification with allyl alcohol.
Stage One: Synthesis of Isoamyloxyacetic Acid
In the first stage, isoamyl alcohol is converted to sodium isoamylate. On a plant scale, this is typically accomplished by charging an excess of isoamyl alcohol with concentrated sodium hydroxide and removing the water of neutralization azeotropically under reflux, since the direct use of sodium metal, while chemically cleaner, introduces cost and safety burdens. The isoamyl alcohol itself conveniently serves as both reactant and reaction medium.
Once a substantially anhydrous alkoxide solution has been obtained, sodium chloroacetate is introduced gradually at a controlled temperature, typically in the range of 90 to 110 °C. The alkoxide displaces chloride in a classical SN2 fashion, generating sodium isoamyloxyacetate and sodium chloride.
Stage Two: Esterification with Allyl Alcohol
The second stage is an acid-catalyzed esterification of isoamyloxyacetic acid with allyl alcohol. The acid and a modest molar excess of allyl alcohol, commonly 1.2 to 1.5 equivalents, are charged to a stirred reactor together with a catalytic quantity of p-toluenesulfonic acid or sulfuric acid, generally 0.5 to 1.5 percent by weight.
Bulk Allyl Amyl Glycolate Suppliers
The supply for allyl amyl glycolate is expected to remain healthy, supported by the ingredient’s entrenched role in perfumery and by sustained growth in scented consumer products across emerging markets. Top allyl amyl glycolate suppliers like IFF, Ernesto Ventos, Firmenich, Symrise, Givaudan, and Lluch Essence supply this ingredient for flavor and fragrance applications. Chinese suppliers of allyl amyl glycolate compete primarily on price and serve buyers with robust in-house quality control capabilities.
Sinofi is a bulk allyl amyl glycolate supplier in China, and we have a warehouse with 1,200 square meters for high-quality allyl amyl glycolate. We sell different grades of allyl amyl glycolate at wholesale prices, serving end-users in fine fragrances, personal care, air fresheners, detergents, and household cleaning industries.
Supply Chain of Allyl Amyl Glycolate
The supply chain of allyl amyl glycolate illustrates, in miniature, the economics of the specialty aroma chemical industry: commodity petrochemical inputs, a technically accessible but quality-critical synthesis step, a concentrated and increasingly Asia-weighted manufacturing base, a distribution tier that adds genuine value through documentation and availability, and a downstream market in which grams of material shape the identity of products sold in the billions of units.
Supply Chain Structure
The allyl amyl glycolate value chain follows the classic architecture of a specialty aroma chemical, with five distinct tiers:
- Petrochemical feedstocks (propylene, chlorine, fusel oils)
- Key intermediates (allyl alcohol/allyl chloride, isoamyl alcohol, chloroacetic or glycolic acid derivatives)
- Aroma chemical synthesis (specialty manufacturers in China, Europe, and the United States)
- Distribution and compounding (global distributors, regional traders, fragrance and flavor houses)
- End markets (fine fragrance, personal care, home care, and limited flavor applications)
Value concentrates progressively as material moves down this chain. A commodity feedstock worth a few dollars per kilogram becomes a specialty ester selling at a substantial multiple once purity, olfactive quality, and regulatory documentation are attached, and the fragrance compound into which it is blended commands a further premium still.
Wholesale and Buy Allyl Amyl Glycolate in Bulk
Purchasing allyl amyl glycolate in wholesale quantities offers several tangible advantages. First, unit pricing improves substantially at volume, with tiered discounts typically available at the 25-kg drum, 200-kg drum, and full-pallet or IBC levels. Second, bulk contracts allow buyers to lock in pricing over a defined period, insulating production budgets from spot-market volatility in raw material and freight costs. Third, consolidated shipments reduce per-kg logistics expenses and administrative overhead. Finally, maintaining an adequate buffer inventory of a workhorse ingredient protects production schedules against supplier disruptions, port delays, and seasonal demand surges.
Defining Quality Specification
Before soliciting quotations, allyl amyl glycolate buyers should establish a clear internal specification. For allyl amyl glycolate, the essential parameters generally include the following: assay purity (commonly 98% by gas chromatography), appearance, odor conformity against an approved reference standard, refractive index, specific gravity, and acid value. Requesting a Certificate of Analysis (COA) for each production lot is standard practice, and it is prudent to require pre-shipment samples for olfactory and analytical evaluation before approving a new supplier or a new lot for release.
Odor conformity deserves particular emphasis. Because allyl amyl glycolate is frequently a character-defining note in a formulation, even minor variations in trace impurities can shift the olfactory profile of a finished product. A disciplined sample-approval protocol, ideally involving both the quality laboratory and an evaluator or perfumer, prevents costly reformulation issues downstream.
Vetting and Qualifying Suppliers
When qualifying a wholesale source, manufacturing certifications such as ISO 9001 or conformity with industry bodies are very important. Beyond headline price, a well-structured wholesale agreement should address minimum order quantities, volume rebates and price-adjustment mechanisms tied to transparent indices.
As a bulk manufacturer and supplier of allyl amyl glycolate in China, we wholesale this ingredient to end users in fine fragrances, personal care, air fresheners, detergents, and household cleaning industries. We also supply allyl amyl glycolate to small customers. Normally, they want to buy allyl amyl glycolate in small quantities. To serve them, we can sell allyl amyl glycolate at bulk prices and provide a one-stop purchasing service.
Allyl Amyl Glycolate Prices (USD/Kg)
Fragrance Grade Allyl Amyl Glycolate Prices (GC Content >=99.0%)
| Volume | Unit Price | Shipment |
| 50g | 6 USD | Express |
| 500g | 32 USD | Express |
| 1Kg | 47 USD/Kg | Express |
| 25Kg | 33 USD/Kg | Express |
| 100Kg | 29 USD/Kg | Express / Sea |
| 200Kg-Above | negotiable | Express / Sea |
Allyl amyl glycolate clusters in a wide US$20–50 per kilogram range depending on purity, order size, and supplier credibility, with credible drum-to-ton quotations toward the upper single digits and teens. Small-lot perfumery pricing in the West is an order of magnitude higher on a per-gram basis. Several very low listings on B2B platforms (for example, US$0.80–2.60/kg, or “US$1.00” per ton) are placeholder figures used to solicit inquiries rather than genuine transaction prices.
Furthermore, the above price quotations of allyl amyl glycolate do not include the express fee. This is because the shipment cost may exceed the sample value of allyl amyl glycolate. However, the bulk wholesale prices of allyl amyl glycolate will be much lower than those of small orders. Please contact us for more details.
Allyl Amyl Glycolate Specification
| Appearance | Colorless clear liquid. |
| Odor: | Strong fruity aroma with slight pineapple-like. |
| Purity (GC) | >=99% |
| Refractive Index (20°C) | 1.428 – 1.433 |
| Specific Gravity (at 25℃/25℃) | 0.935 – 0.945 |
| Acid Value (mg KOH/g) | <=1.0 |
Allyl Amyl Glycolate Uses
Allyl amyl glycolate occupies an important place in the modern perfumer’s palette. Its uses span fine fragrance, personal care, and household products, where it serves as a powerful source of fruity-green freshness, a builder of pineapple and tropical accords, and a modernizing accent that enlivens citrus, aromatic, and aquatic compositions.
Uses in Fine Fragrance
The principal application of allyl amyl glycolate is in fine fragrance. Perfumers employ it to construct pineapple and tropical fruit accords, to add lift and sparkle to citrus top notes, and to lend a green, dewy effect to fruity-floral and fougère compositions. It pairs effectively with materials such as dihydromyrcenol, citrus oils, galbanum, marine notes, and lavender, and it is frequently found in masculine “sport” fragrances as well as in modern unisex and feminine fruity compositions. Its association with prominent pineapple-forward fragrances has further cemented its reputation as a cornerstone of the contemporary fruity-fresh genre. Because of its strength, it is generally dosed at fractions of one percent of a fragrance concentrate, where even trace amounts can define the opening impression of a perfume.
Uses in Functional and Consumer Products
Beyond fine fragrance, allyl amyl glycolate is widely used in functional perfumery, meaning the scenting of consumer and household products. Its stability, diffusion, and cost-effectiveness make it suitable for shampoos, shower gels, bar and liquid soaps, deodorants, and other personal care formats, where it delivers an immediate impression of freshness and cleanliness. It also appears in household applications such as laundry detergents, fabric softeners, dish care products, air fresheners, and all-purpose cleaners. In these categories, its ability to bloom in aqueous and surfactant systems and to survive mildly alkaline conditions is particularly advantageous, allowing the fruity-green character to remain perceptible both in the product and on fabrics or skin after use.
Allyl Amyl Glycolate Benefits
Allyl amyl glycolate endures on the perfumer’s organ because it combines qualities that are rarely found together: a memorable and versatile odor profile, extraordinary strength and diffusion, dependable performance in functional bases, and economic efficiency at typical use levels. From the landmark fresh fragrances of the late twentieth century to today’s tropical and solar compositions, it continues to shape the way freshness and fruitiness are expressed in scent. For formulators seeking impact, character, and versatility from a single raw material, allyl amyl glycolate remains one of the most rewarding tools available.
A Distinctive and Instantly Recognizable Odor Profile
The foremost benefit of allyl amyl glycolate is its singular olfactory character. Few materials deliver such a convincing impression of fresh, unripe pineapple combined with sharp green intensity. This duality allows the ingredient to serve two creative purposes at once: it lends realism and juiciness to tropical fruit accords, and it injects a bracing, energetic greenness into compositions that might otherwise feel flat. The material rose to prominence in the late 1980s and 1990s, when it became a signature element of the fresh, sporty, and aquatic styles exemplified by fragrances such as Davidoff Cool Water and Aramis New West. Its association with that era of vibrant, athletic freshness remains a creative shorthand that perfumers continue to draw upon today.
Exceptional Impact and Diffusion at Low Dosage
Allyl amyl glycolate is a high-impact material, meaning that trace quantities are sufficient to influence the character of an entire formula. In many fine fragrance compositions, it is used at fractions of one percent, yet its effect on the opening of the fragrance is unmistakable. This potency translates into two practical benefits. First, it acts as a top-note booster, amplifying lift and radiance so that a fragrance projects strongly in the critical first moments after application. Second, its efficiency makes it economical: because so little is required to achieve the desired effect, the cost contribution of the ingredient to a finished formula is typically modest relative to its creative value.
Versatility Across Fragrance Families
Although allyl amyl glycolate is most closely associated with fruity and green effects, its usefulness extends across a wide range of fragrance families. In fougère and aromatic compositions, it sharpens lavender and herbal notes and pairs naturally with materials such as dihydromyrcenol. In tropical and gourmand accords it reinforces pineapple, mango, and exotic fruit themes. In floral bouquets, a restrained dose adds sparkle and a modern, dewy freshness. It also harmonizes well with galbanum, citrus materials, and marine notes, which explains its ubiquity in aquatic and ozonic styles. This adaptability allows a single raw material to serve many creative briefs, simplifying palette management for fragrance houses.
Strong Performance in Functional Products
Beyond fine fragrance, allyl amyl glycolate offers substantial benefits in functional perfumery, the branch of the industry devoted to scenting household and personal care products. The material performs reliably in demanding bases such as shampoos, shower gels, bar soaps, fabric softeners, and detergents, where it contributes an immediate impression of freshness and cleanliness at the point of use. Its powerful bloom in the presence of water makes it particularly valuable in rinse-off products, where the fragrance must announce itself quickly during lathering or laundering. Manufacturers value ingredients that deliver consistent hedonic impact across diverse product chemistries, and allyl amyl glycolate has earned a durable place in this category.
A Lotus Fragrance for Laundry Detergent Using Allyl Amyl Glycolate
Include the following ingredients (by weight, total 100%):
Osmanthus absolute, 0.020; Jasmine absolute, 0.060; Michelia leaf oil, 0.050; Vetiver oil, 0.060; Geranium oil, 0.100; Eucalyptus oil, 0.100; Indole, 0.50; Nerol, 0.30; Cyclamen aldehyde, 0.50; Citronellol, 0.50; Cinnamyl alcohol, 0.80; Geraniol, 1.00; Linalool oxide, 0.015; Benzaldehyde, 0.015; Cis-3-Hexenyl acetate, 0.015; Allyl amyl glycolate, 0.055; Benzyl salicylate, 0.100; Phenylethyl alcohol, 7.20; Terpineol, 2.00; Linalool, 4.70; Methyl dihydrojasmonate, 1.00; Alpha-Hexylcinnamaldehyde, 7.20; Butylated hydroxytoluene, 0.50; Dipropylene glycol, 10.000; Diethyl phthalate, 63.210;
In conclusion, allyl amyl glycolate occupies an important position in fine fragrances, personal care, air fresheners, detergents, and household cleaning industries. As a bulk allyl amyl glycolate manufacturer and supplier in China, we sell different grades of allyl amyl glycolate at wholesale prices to clients around the world.